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Phosphorus Compounds (4):
Recent article
Phosphorus Compounds
Abstract
In this study, hexachlorocyclotriphosphazene, N(3)P(3)Cl(6) (cylotriphosphazene), was reacted with hydrophilic and hydrophobic groups to synthesize amphiphilic phosphazene derivatives (4-12). Cylotriphosphazene was reacted triethylene glycol monomethyl ether (TEGME), dipropylene glycol monomethyl et...
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PMID: 20938539
PDF is available here.
PDF is available here.
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Abstract
We have determined the reaction path of the phosphorylation step using high-level QM/MM calculations, and have also calculated the geometry of a complex with a transition state analogue (TSA) that has been suggested to be the actual species in the crystal. The protein crystalline environment has bee...
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PMID: 20602355
PDF is available here.
PDF is available here.
Abstract
The strong directing ability of the N,N,N',N'-tetramethyldiaminophosphorodiamidate group has been used to achieve selective metalations on various heterocycles such as pyridines, quinolines and quinoxalines with TMP-derived bases like TMPMgCl x LiCl, TMP(2)Mg x 2 LiCl, and TMP(2)Zn x 2 MgCl(2) x 2 L...
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PMID: 20356104
PDF is available here.
PDF is available here.
Chemical Communications (46)13 2010
Abstract
A facile oxidation for the clean conversion of benzo[b]thiophenes to their corresponding sulfones is described employing an aqueous solution of H(2)O(2) and P(2)O(5); the solution can be prepared and stored on a multi-gram scale with a shelf-life of up to two weeks.
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PMID: 20234935
PDF is available here.
PDF is available here.
Optics Express (18)5 2010
Abstract
The sensitivities of resonant wavelengths of photonic crystal (PhC) membrane nanocavities with embedded InAs quantum dots to the ambient refractive index are reported for use in (bio) chemical sensing. The resonances for the different modes of several point-defect type cavities are obtained by photo...
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PMID: 20389419
PDF is available here.
PDF is available here.
Abstract
New organotin substituted alpha-anilinomethylphosphonates were prepared and were characterized by FT-IR, 1H- and 13C-NMR spectroscopy and elemental microanalysis.
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PMID: 20335990
PDF is available here.
PDF is available here.
Abstract
The purpose of this study was to investigate the enamel remineralization potential of two toothpastes, one of which was based on Recaldent (CPP- ACP) and the other on NovaMin (Calcium-sodium-phosphosilicate). Human permanent molar teeth were subjected to three consecutive demineralization cycles. The...
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PMID: 21638965
PDF is available here.
PDF is available here.
Gastroenterology Nursing (33)1 2010
Abstract
Abstract
A new low-density lipoprotein (LDL) adsorbent with phosphate groups as the ligand was prepared in this study. Macroporous poly(vinyl acetate-co-triallyl isocyanurate) microspheres were prepared using a free-radical suspension polymerization method. A hydrolysis reaction in sodium hydroxide/methanol...
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PMID: 19934485
PDF is available here.
PDF is available here.
Abstract
Information on the chemical composition of sediment phosphorus (P) is fundamental to understanding P dynamics and eutrophication in lake ecosystems. In this study, the surface (10 cm) sediments were collected from seven lakes representing two contrasting ecological areas in China: the middle and low...
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PMID: 19141826
PDF is available here.
PDF is available here.
Abstract
31P MR spectroscopy (MRS) in the detection of phosphocholine (PC), glycerolphosphocholine (GPC), phosphorylelthanolamine (PE), and glycerolphosphoethanolamine (GPE) compounds has shown clinical potential at 1.5T for several human diseases. The use of (1)H to (31)P polarization transfer can improve t...
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PMID: 19030163
PDF is available here.
PDF is available here.
Abstract
The pH-controlled assembly/disassembly of a nanoscale {P4W52O178}24- cluster at pH 2 to a {P4W44O152}20- cluster at pH 3-5 via a {P3W39O134}19- cluster species at pH 2-3 to finally give {P2W19O69(OH2)}14- at pH 6 is reported. This process can be traced in the solid state crystallographically and in...
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PMID: 18937461
PDF is available here.
PDF is available here.
Abstract
A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.
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PMID: 18681433
PDF is available here.
PDF is available here.
Abstract
A fast and efficient synthesis of N(alpha)-protected thiopeptide esters from the corresponding peptide esters using P(2)S(5) as thionating agent assisted by ultrasonication has been described. The conversion of peptide bond into thioamide was complete in 20-40 min at rt. The reaction was accomplishe...
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PMID: 18524664
PDF is available here.
PDF is available here.
Journal of Hazardous Materials (156)1-3 2008
Abstract
This paper describes the solidification and stabilization of electroplating sludge treated with a high-performance binder made from portland type-I cement, municipal solid waste incineration fly ash, and lighting phosphor powder (called as cement-fly ash-phosphor binder, CFP). The highest 28-day unc...
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PMID: 18207638
PDF is available here.
PDF is available here.
Journal of Organic Chemistry (73)15 2008
Abstract
Small libraries of di-, tri-, and tetragalactosyl clusters were efficiently synthesized using combinatorial methodology, on solid support, by click chemistry assisted by microwaves, starting from different poly alkyne DNA-based scaffolds and two galactosyl azide derivatives. The scaffold was synthes...
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PMID: 18598084
PDF is available here.
PDF is available here.
Abstract
Various metal complexes (e.g., lanthanides, early transition metals, and alkali metals) can serve as catalyst precursors for the catalytic addition of alkyne C-H, amine N-H, and phosphine P-H bonds to carbodiimides, to give a new family of propiolamidines, guanidines, and phosphaguanidines, some of...
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PMID: 18452004
PDF is available here.
PDF is available here.
Environmental Science (29)5 2008
Abstract
The change of phosphorus forms in sediments was studied and the possible path of transformation from mobile phosphorus into refractory forms was discussed under the conditions of sediments re-suspension, using sediments and overlying water from the trophic canal in the campus as material. The result...
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PMID: 18624195
PDF is available here.
PDF is available here.
Environmental Science (29)5 2008
Abstract
Adsorption capacity, isotherms and kinetics of phosphate onto the 18 surface sediments taken from Nansi Lake and its main inflow rivers were investigated in laboratory, and the relationships between physical and chemical properties of the sediments and their phosphate adsorption characteristics are...
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PMID: 18624196
PDF is available here.
PDF is available here.
Environmental Science (29)5 2008
Abstract
The forms of phosphorus in the surface sediments were extracted and determined sequentially with ethylene dinitrilo tetracetic acid (EDTA) technique in three urban shallow lakes: Lake Xuanwu, Lake Mochou and Lake Daming. The results showed that the iron and calcium-bound phosphate, about accounting...
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PMID: 18624197
PDF is available here.
PDF is available here.
Journal of Hazardous Materials (153)1-2 2008
Abstract
A new technique to remove Pb(2+) ions from a solution by using a phosphosilicate glass was introduced. When the phosphosilicate glass with an invert glass composition [mol%: 44.9%SiO(2)-5.2%P(2)O(5)-23.7%Na(2)O-26.2%CaO] was reacted with the solution containing Pb(2+) ions. The glass surface turned...
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PMID: 17904733
PDF is available here.
PDF is available here.
The Journal of Chemical Physics (128)13 2008
Abstract
The dissociative recombination of OPCl+ and OPCl2+ has been studied at the storage ring CRYRING. The rate constants as a function of electron temperature have been derived to be 7.63 x 10(-7)(Te/300)(-0.89) and >1.2 x 10(-6)(Te/300)(-1.22) cm3s(-1), respectively. The lower limit quoted for the latte...
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PMID: 18397065
PDF is available here.
PDF is available here.
Abstract
This work consists on the evaluation of the in vitro performance of Ti6Al4V samples PLD (pulsed laser deposition) coated with hydroxyapatite, both pure and mixed with a CaO-P2O5 glass. Previous studies on immersion of PLD coatings in SBF, showed that the immersion apatite films did not present the u...
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PMID: 18058197
PDF is available here.
PDF is available here.
Abstract
Ti K-edge XANES (X-ray absorption near edge structure) spectroscopy has been used to study the local coordination of titanium in biocompatible and bioresorbable TiO2-CaO-Na2O-P2O5 glasses. Both conventional melt-quenched glasses of composition (TiO2)x(CaO)0.30(Na2O)0.20-x(P2O5)0.50, where x = 0.01,...
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PMID: 18157713
PDF is available here.
PDF is available here.
Abstract
Binding human serum albumin (HSA) of three polyoxometalates (POMs) with the Wells-Dawson structure, alpha(2)-[P2W17O61]10- (abbreviated as alpha(2)-P2W17) and two of its metal-substituted derivatives, alpha(2)-[NiP2W17O61]8- and alpha(2)-[CuP2W17O61]8- (alpha(2)-P2W17Ni and alpha(2)-P2W17Cu, respect...
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PMID: 18266320
PDF is available here.
PDF is available here.
Journal of Dentistry (36)3 2008
Abstract
The highest yield was obtained (62%) when azeotropic distillation was used, while the reaction with molecular sieves was not feasible. The phosphoric moiety attachment to the monomer was successfully performed with a quantitative yield that reached around 100%. The acidic monomer concentration signi...
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PMID: 18243472
PDF is available here.
PDF is available here.
Mikrobiologiia (77)3 2008
Abstract
In the course of pilot trials of biotechnologies for the enhancement of oil recovery in the Gangxi bed of the Dagang oil field (China), microbiological processes were investigated. The biotechnologies were based on injection into the petroleum reservoir of different oxygen sources (H2O2 solution or...
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PMID: 18683655
PDF is available here.
PDF is available here.
Journal of Oleo Science (57)9 2008
Abstract
Fatty acid amides like erucamide are mainly used for lubrication and as slip agent to decrease friction in polymer and plastic industry. Erucamide is normally synthesized by ammonolysis of triglycerides or fatty acids at 200 degrees C and at high pressure (345-690 kPa.). However using urea in place...
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PMID: 18685229
PDF is available here.
PDF is available here.
Journal of Physical Chemistry B (111)51 2007
Abstract
We have focused on structural features which can have a direct role in the bioactive mechanism of dissolution and bone bonding. The higher affinity of modifier Na and Ca cations for coordinating phosphate rather than silicate, together with the formation of P-O-Si linkages, lead to increasing repoly...
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PMID: 18047313
PDF is available here.
PDF is available here.
Abstract
Palladium complexes bearing phospholane 1 and phosphetane 2-4 ligands have been synthesised to be used as catalyst precursors in the asymmetric methoxycarbonylation of vinyl arenes. Single crystals of the complex [PdCl2(2)2] II were obtained from a toluene solution and analysed by X-ray crystallogra...
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PMID: 18043812
PDF is available here.
PDF is available here.
Abstract
We found that bis-phospholane-type ligands, such as bis-diazaphospholanes and bis-phospholanes, can lead to very high regio- and enantioselectivities for several different substrates....
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PMID: 17997526
PDF is available here.
PDF is available here.
Chemosphere (69)10 2007
Abstract
To evaluate both the natural and anthropogenic influences on surface waters of Guadalquivir River (SW-Spain), concentrations of dissolved trace metals (Mn, Co, Ni, Cu, Cd, Zn, and Pb), inorganic nutrients (N-NH(4)(+), N-NO(3)(-), N-NO(2)(-), and P-PO(4)(3-)) and other variables as conductivity, pH,...
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PMID: 17631380
PDF is available here.
PDF is available here.
Abstract
All patients underwent follow-up imaging 6 months after the start of treatment; 25 patients, 12 months; and 10 patients, 18 months after the start of treatment. According to the Ishak histologic scoring system, nine patients had mild hepatitis; 30 patients, moderate to severe hepatitis; and eight pa...
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PMID: 17885051
PDF is available here.
PDF is available here.
Abstract
The present paper describes an effort for developing the total maximum daily load (TMDL) for phosphorus and a load reduction strategy for the Feitsui Reservoir in Northern Taiwan. BASINS model was employed to estimate watershed pollutant loads from nonpoint sources (NPS) in the Feitsui Reservoir wat...
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PMID: 17171261
PDF is available here.
PDF is available here.
Science of the Total Environment (380)1-3 2007
Abstract
The dynamics of nitrogen (N), phosphorus (P) and carbon (C) accumulation in the filter material of a horizontal subsurface constructed wetland (HSSF CW; established in 1997) and in a specially designed oil-shale ash filter (2002) for P retention have been studied. Concentrations of N, P and C in fil...
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PMID: 17081592
PDF is available here.
PDF is available here.
Science of the Total Environment (380)1-3 2007
Abstract
The processes that affect removal and retention of nitrogen during wastewater treatment in constructed wetlands (CWs) are manifold and include NH(3) volatilization, nitrification, denitrification, nitrogen fixation, plant and microbial uptake, mineralization (ammonification), nitrate reduction to am...
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PMID: 17078997
PDF is available here.
PDF is available here.
Science of the Total Environment (380)1-3 2007
Abstract
This study was aimed at determining the spatial and temporal variation of P distribution in sediment of an artificial wetland for sewage and industrial wastewater treatment, and the fraction that is potentially involved in the P exchange processes. Influent, effluent, macrophytes and sediment at the...
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PMID: 17229453
PDF is available here.
PDF is available here.
Science of the Total Environment (380)1-3 2007
Abstract
We conclude that continuous water flow and stable water levels are desired for flooded peatlands to prevent high concentrations of ammonium and phosphate and to utilize the potential for nitrate retention. In degenerated peatlands, flooding should only be regarded as an easy technological solution i...
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PMID: 17118429
PDF is available here.
PDF is available here.
Abstract
Derivatives of the tri-spirane pentaerythritoxy-cyclophosphazene compound, 1, have been used to investigate the stereogenic properties of spiranes combined with four equivalent conventional centres of chirality. In compound 1 the two inner rings are carbocyclic and symmetrical and the two outer ring...
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PMID: 17502937
PDF is available here.
PDF is available here.
NMR in Biomedicine (20)4 2007
Abstract
Studies of transgenic mice provide powerful means to investigate the in vivo biological significance of gene products. Mice with an under- or overexpression of enzymes involved in high-energy phosphoryl transfer (approximately P) are particulary attractive for in vivo MR spectroscopy studies as the...
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PMID: 17274105
PDF is available here.
PDF is available here.
Abstract
A new class of thermosensitive micellar cyclotriphosphazenes has been synthesized by stepwise nucleophilic substitutions of hexachlorocyclotriphosphazene with a hydrophilic methoxy poly(ethylene glycol) (MPEG) and a hydrophobic oligopeptide selected from tetra- to hexapeptides, and characterized by...
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PMID: 17382421
PDF is available here.
PDF is available here.
Abstract
Electrophoresis (28)10 2007
Abstract
A CE method was developed for the simultaneous determination of Zr(IV) and Hf(IV) at trace levels. A lacunary Keggin-type [PW(11)O(39)](7-) ligand reacted quantitatively with a mixture of trace amounts of Zr(IV) and Hf(IV) to form the so-called ternary Keggin-type anions [P(Zr(IV)W(1...
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PMID: 17447242
PDF is available here.
PDF is available here.
Abstract
Mesoporous SiO2-P2O5 films were synthesized from the vapor phase onto a silicon substrate. First, a precursor solution of cetyltrimethylammonium bromide (C16TAB), H3PO4, ethanol, and water was deposited on a silicon substrate by a spin-coating method. Then, the C16TAB-H3PO4 composite film was treate...
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PMID: 17373837
PDF is available here.
PDF is available here.
Abstract
Bioactive glasses have been used as a graft material that can stimulate the formation of a new bone. In vitro tests usually give sensible indications about the potential bioactivity of these glasses. In the present work the influence of egg albumin on the formation of a Ca-P precipitate on a glass o...
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PMID: 17546419
PDF is available here.
PDF is available here.
Dental Materials (23)4 2007
Abstract
All products contain ammonium dihydrogen phosphate as the acid phosphate required for the setting reaction. All set by the formation of struvite and significant amounts of amorphous magnesium orthophosphate. In three products, lesser amounts of newberyite were present and in another the equivalent a...
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PMID: 16563493
PDF is available here.
PDF is available here.
Abstract
A second, polymorphic, form of the previously reported compound 4,4,6,6-tetrachloro-2,2-(2,2-dimethylpropane-1,3-dioxy)cyclotriphosphazene, C(5)H(10)Cl(4)N(3)O(2)P(3), is now reported. The molecular structures of these two compounds are similar, aside from minor conformational differences. However,...
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PMID: 17339718
PDF is available here.
PDF is available here.
Abstract
Nuclear magnetic resonance (NMR) spectroscopy of the heart is normally carried out using whole heart preparations under coronary perfusion. In such preparations, either radical changes in ionic composition of the perfusate or applications of numerous drugs would affect coronary microcirculation. Thi...
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PMID: 17040966
PDF is available here.
PDF is available here.
Abstract
The water content of six different substances was determined by means of five different methods. The methods used were loss on drying, thermogravimetry (coupled with DSC), a new phosphorous-pentoxide method, direct Karl-Fischer titration and the Karl-Fischer oven. A combination of direct Karl-Fische...
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PMID: 16956740
PDF is available here.
PDF is available here.
Abstract
Abstract
Layering solutions of P(4)S(3) in CH(2)Cl(2) with solutions of CuCl or CuI in CH(3)CN gives the coordination polymers (P(4)S(3))(3)(CuCl)(7) (1), (P(4)S(3))(2)(CuCl)(3) (2), (P(4)S(3))(CuI) (3) and (P(4)S(3))(CuI)(3) (4), respectively, after slow diffusion. The yellow compounds were characterised by...
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PMID: 17705327
PDF is available here.
PDF is available here.
Abstract
We investigate aspects of the reaction mechanism of Cdk2 by gas-phase density functional calculations, classical molecular dynamics, and Car-Parrinello QM/MM simulations. We focus on the role of the conserved Asp127 and on the nature of the phosphoryl transfer reaction mechanism catalyzed by Cdk2. O...
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PMID: 17636466
PDF is available here.
PDF is available here.
Abstract
The present paper shows methods to suppress radon emanation from artificial porous materials such as phosphorous fertiliser or diatomaceous earth with a small amount of radium. The basic concept of suppression is making the radon emanation mechanism 'null', which comes from the fact that recoil is t...
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PMID: 17893080
PDF is available here.
PDF is available here.
Inorganic Chemistry (45)26 2006
Abstract
The stable mononuclear Ni(III)-thiolate complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]- (L = SePh (2), Cl (3), SEt (4), 2-S-C4H3S (5), CH2CN (7)) were isolated and characterized by UV-vis, EPR, IR, SQUID, CV, 1H NMR, and single-crystal X-ray diffraction. The increased basicity (electronic density) of th...
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PMID: 17173448
PDF is available here.
PDF is available here.
Water Research (40)20 2006
Abstract
Phosphorus (P) composition in alkaline sediment extracts from three Swedish oligotrophic mountain lakes was investigated using 31P-NMR spectroscopy. Surface sediments from one natural lake and two mature reservoirs, one of which has received nutrient additions over the last 3 years, were compared wi...
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PMID: 17070896
PDF is available here.
PDF is available here.
Abstract
Journal of Chromatography A (1132)1-2 2006
Abstract
High-performance liquid chromatographic (HPLC) methods have been developed for investigating the stereogenic properties of two analogous series of dibenzylamino derivatives of cyclotriphosphazene containing either one or two equivalent stereogenic centres. Separation of the enantiomers of all the ra...
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PMID: 16965786
PDF is available here.
PDF is available here.
Abstract
We found that blockade of PLCgamma enzymatic activity also blocks early osteoclast development and function. Importantly, targeted deletion of Plcg2 in mice led to an osteopetrotic phenotype. PLCgamma2, independent of PLCgamma1, was required for receptor activator of NF-kappaB ligand-induced (RANKL-...
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PMID: 17053833
PDF is available here.
PDF is available here.
Abstract
The prebiotic synthesis of phosphorus-containing compounds-such as nucleotides and polynucleotides-would require both a geologically plausible source of the element and pathways for its incorporation into chemical systems on the primitive Earth. The mineral apatite, which is the only significant sou...
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PMID: 17008215
PDF is available here.
PDF is available here.
Journal of Organic Chemistry (71)20 2006
Abstract
A new phosphorylated linear nitrone N-(4-hydroxybenzyliene)-1-diethoxyphosphoryl-1-methylethylamine N-oxide (4-HOPPN) was synthesized, and its X-ray structure was determined. The spin trapping ability of various kinds of free radicals by 4-HOPPN was evaluated. Kinetic study of decay of the superoxid...
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PMID: 16995683
PDF is available here.
PDF is available here.